Flumecinol and related compounds can, without derivatization, be separated into their enantiomers by gas chromatography on cyclodextrin phases; permethylated P-cyclodextrin dissolved in OV- 1701 can be particularly recommended. Thermodynamic data describing the different intensities of interaction o
Methacrylate resins for the gas chromatographic separation of strongly polar compounds
✍ Scribed by L. Kalusová; R. Komers
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 593 KB
- Volume
- 91
- Category
- Article
- ISSN
- 1873-3778
No coin nor oath required. For personal study only.
✦ Synopsis
Polymerized 2-cyanoethyl methacrylate (KEM) has been tested as a stationary phase for gas-solid chromatography.
Its thermal stability has been investigated and the usable range defined. The specific retention volumes, V,,, of the C1-Cs fatty acids and water have been measured and some thermodynamic quantities (AH) have been calculated, providing information on the nature and the magnitude of the sorbate-sorbent interactions.
The optimum conditions for the separation of the C1-Cs acids and water have been determined.
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