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Metal–organic co-ordination frameworks based on mixed N- and O-donor ligands: crystal structures of [Co(phth)2(bipy)] and [Co2(mal)2(bipy)(H2O)2] (phth = phthalate, mal = malonate, bipy = 4,4′-bipyridine) †

✍ Scribed by Lightfoot, Philip; Snedden, Alan


Book ID
120196341
Publisher
The Royal Society of Chemistry
Year
1999
Tongue
English
Weight
440 KB
Volume
20
Category
Article
ISSN
1472-7773

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✍ Roberto Della Pergola; Annalisa Sironi; Carlo Manassero; Mario Manassero 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 459 KB 👁 1 views

## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip