Metalmetal spin coupling through chalcogenides. Correlation of 2J(119Sn, 119Sn) with molecular structure. Crystal structure of [(2-MeC6H4CH2)3Sn]2O and [(2-MeC6H4)3Sn]2O
✍ Scribed by T.P. Lockhart; H. Puff; W. Schuh; H. Reuter; T.N. Mitchell
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 850 KB
- Volume
- 366
- Category
- Article
- ISSN
- 0022-328X
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Tetrapropylammonium and -phosphonium ions, nPr 4 E ؉ , react readily with the polymeric super-Prussian blue derivatives [(Me 3 Sn) 3 M(CN) 6 ] (M ؍ Co, Ir), which are built up of in5nite [ +M+CN+Sn+NC] + chains, a4ording the dimorphic supramolecular assembly [(nPr 4 E)(Me 3 Sn) 2 M(CN) 6 ' 2H 2 O]