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Metal–Metal Interaction and Flexible Motion of Triple-Decker Polypyridyl Platinum(II) and Palladium(II) Complexes

✍ Scribed by Yuta Kajitani; Prof. Kiyoshi Tsuge; Prof. Yoichi Sasaki; Prof. Masako Kato


Book ID
112020360
Publisher
John Wiley and Sons
Year
2012
Tongue
English
Weight
537 KB
Volume
18
Category
Article
ISSN
0947-6539

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Rhodium(I), iridium(I), palladium(lI) and platinum(II) complexes of the phosphinoamide ligands, Ph2PCH2CONHR (R = H, HDPA; Me, MDPA; Ph, PDPA) were prepared and characterized by using conductivity data, i.r., 1H and31P(H) n.m.r, spectral data. Reaction of the ligands with MCI(PPh3) 3 and MCI(CO)(PPh