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Metal−Metal Bonding in M 2 Cl 6 (H 2 PCH 2 PH 2 ) 2 , M 2 Cl 6 (PH 3 ) 4 , and M 2 Cl 104- (M = Cr, Mo, W) Edge-Shared Dimer Systems

✍ Scribed by Stranger, Robert; Lovell, Timothy; McGrady, John E.


Book ID
126951056
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
183 KB
Volume
38
Category
Article
ISSN
0020-1669

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## Abstract The reductive carbonylation of ruthenium and osmium halides in the presence of cobalt and iron surfaces was studied. In these surface‐assisted reactions the metal surface plays an active role in releasing metal ions, which can be used for the in situ synthesis of mixed‐metal compounds.