𝔖 Bobbio Scriptorium
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Metal–metal bond energies in Mo2, Mo2Cl, and Mo2(O2CH)4

✍ Scribed by Joe G. Norman Jr.; P. Barry Ryan

Publisher
John Wiley and Sons
Year
1980
Tongue
English
Weight
385 KB
Volume
1
Category
Article
ISSN
0192-8651

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✦ Synopsis

Previous attempts to determine the strengths of multiple metal-metal bonds are reviewed. Estimates of 73 and 97 kcal/mole for the Mo-Mo bond energies in MoZCle-and Mo2(02CH)4, respectively, are obtained by combining the known experimental bond energy in M o ~ (96.5 f 5 kcal/mole) with the results of S C F -X a -S W calculations on Mo2, Mo2Cle-, and Mo2(02CH)4. Possible errors in the estimates are discussed. It is noted that the quadruple bonds in the complexes are predicted stronger per component than the sextuple bond in the diatomic.

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The K4Mo2Cl8-NOCl, Mo2(C2H3O2)4-NOCl, an
The K4Mo2Cl8-NOCl, Mo2(C2H3O2)4-NOCl, and [(C2H5)N]3Mo2Cl9-NOCl systems in ethyl acetate
✍ K.E. Voss; J.D. Hudman; J. Kleinberg 📂 Article 📅 1976 🏛 Elsevier Science 🌐 English ⚖ 639 KB

The behavior of the K&02C18-NOCI, Moz(C,H3-02)4-NOCl, and [(CzH5).,N] &o&,-NOCI systems in ethyl acetate has been investigated. In every case, only products were found in which the molybdenummolybdenum multiple bonds of the starting complexes had been cleaved, After appropriate work-up of the K&02C1