X-ray Crystallographic Studies of a Bimetalliccis-Mo(CO)4(PPh2NH2CH2CH2N=CHC6H4-o-O)2Cu Complex, the Starting Material,cis-Mo(CO)4(PPh2Cl)2, and the Reaction Intermediatescis-Mo(CO)4(PPh2NH2CH2CH2NH2)2andcis-Mo(CO)4(PPh2NH2CH2CH2N=CHC6H4-o-OH)2
β Scribed by Christina Duffey; Seth Stepleton; Mary Elizabeth Anderson; Daniel Cox; Marty Ready; Houston Byrd; Carrie A. Bloomfield; Jason L. Freeman; Gary M. Gray
- Publisher
- Springer
- Year
- 2011
- Tongue
- English
- Weight
- 474 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1572-8854
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Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac
A nickel molybdenum phosphate, (NH 3 CH 2 CH 2 NH 3 ) 4 ' (NH 3 CH 2 CH 2 NH 2 ) ' Na ' [Ni 2 Mo 12 O 30 (PO 4 ) (HPO 4 ) 4 (H 2 PO 4 ) 3 ] ' 6H 2 O, involving molybdenum present in V oxidation, has been hydrothermally synthesized and structurally characterized by single crystal X-ray di4raction. De