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Metal–metal and metal–ligand bond strengths in metal carbonyl clusters

✍ Scribed by Andrew K. Hughes; Ken Wade

Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
434 KB
Volume
197
Category
Article
ISSN
0010-8545

No coin nor oath required. For personal study only.

✦ Synopsis

Gillespie FRS on the occasion of his 75th birthday, when despite those years he continues so effectively to shed fresh light and understanding on all he touches, providing new insight (and demolishing cherished myths) on a variety of fundamental chemical topics with a vigour envied by those half his age. We hope this present exploration of patterns lurking in the literature on metal cluster structures and bonding catches the spirit of what Ron himself does so well.

📜 SIMILAR VOLUMES

Metal carbonyl bond strengths: Applicati
Metal carbonyl bond strengths: Applications of photoacoustic calorimetry
✍ Mark Bernstein; John D. Simon; Kevin S. Peters 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 360 KB

Photoacoustic calorimetry has been used to determine the bond dissociation energy of a single carbonyl from the group VI hexacarbonyls in ethanol and cycloheaane. The determined reaction enthalpies are for the photodissociation of a single CO from Cr(CO)h, Mo(CO)e, and W(CO)e in ethanol and cYclohes

Metal cluster topology 14. Fusion of oct
Metal cluster topology 14. Fusion of octahedra in metal carbonyl clusters
✍ R.Bruce King 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 723 KB

Two metal carbonyl cluster octahedra can be fused by sharing a vertex to give an Mrr cluster, by sharing an edge to give an Ml,, cluster, or by sharing a face to give an Mg cluster. In a globally delocalized metal carbonyl cluster consistmg of fused octahedra, vertrces unique to a single octahedron