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Metal carbonyl bond strengths: Applications of photoacoustic calorimetry

✍ Scribed by Mark Bernstein; John D. Simon; Kevin S. Peters

Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
360 KB
Volume
100
Category
Article
ISSN
0009-2614

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✦ Synopsis

Photoacoustic calorimetry has been used to determine the bond dissociation energy of a single carbonyl from the group VI hexacarbonyls in ethanol and cycloheaane. The determined reaction enthalpies are for the photodissociation of a single CO from Cr(CO)h, Mo(CO)e, and W(CO)e in ethanol and cYclohesane are found to be 37,34, and 38 kcal/mole, respectively-l_ Introduction

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