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Metalloporphyrin-catalyzed oxidation of saturated hydrocarbons with sodium chlorite

✍ Scribed by Collman, James P.; Tanaka, Hiroo; Hembre, Robert T.; Brauman, John I.

Book ID
118146917
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
329 KB
Volume
112
Category
Article
ISSN
0002-7863

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Oxidation of saturated hydrocarbons with
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Peroxyacetic acid (PAA) oxidizes alkanes in acetonitrile or acetic acid at 60 β€’ C if a soluble vanadium(V) salt, n-Bu 4 NVO 3 (1), is used as a catalyst. Corresponding ketones, alcohols and alkyl hydroperoxides are the main products. Methane, ethane, propane, cyclohexane, and other higher alkanes we