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Oxidation of Primary Alcohols to Carboxylic Acids with Sodium Chlorite Catalyzed by TEMPO and Bleach

โœ Scribed by Zhao, Mangzhu; Li, Jing; Mano, Eiichi; Song, Zhiguo; Tschaen, David M.; Grabowski, Edward J. J.; Reider, Paul J.


Book ID
120079420
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
101 KB
Volume
64
Category
Article
ISSN
0022-3263

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CuCl catalyzed selective oxidation of pr
โœ Sreedevi Mannam; G. Sekar ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 130 KB

Direct oxidation of primary alcohols to the corresponding carboxylic acids is performed highly efficiently at room temperature with anhydrous tert-butyl hydroperoxide in the presence of a catalytic amount of easily available CuCl under ligand free conditions in acetonitrile. Benzylic alcohols are mo