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Metalloporphyrin-Catalyzed Diastereoselective Epoxidation of Allyl-Substituted Alkenes

โœ Scribed by Chan, Wing-Kei; Wong, Man-Kin; Che, Chi-Ming

Book ID
126446244
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
201 KB
Volume
70
Category
Article
ISSN
0022-3263

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AbstractรAllylic alcohols undergo an efยฎcient process of diastereoselective epoxidation by t-butyl hydroperoxide (TBHP) in n-hexane solution in the presence of catalytic amounts of mono-and bis-cyclopentadienyl titanium(IV) and zirconium(IV) chlorides.