Metallocene–methylaluminoxane catalysts for olefin polymerization. I. Trimethylaluminum as coactivator
✍ Scribed by James C. W. Chien; Bor-Ping Wang
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 578 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0887-624X
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📜 SIMILAR VOLUMES
Metallacyclic metallocene complexes of titanium, zirconium and hafnium can be prepared by hydrogen elimination processes of suitable substituents such as -phenylalkyl or -alkenyl at the aromatic ligands. In some cases, the intermediates containing agostic hydride ligands can be isolated and characte
## Abstract The ethylene polymerization by Cp~2~ZrCl~2~/MAO (Cp = η^5^: cyclopentadienyl; MAO = methyl aluminoxane) and CpZrCl~3~/MAO have been studied. The MW and PD (= __M__~__w__~/__M__~__w__~) of polymers obtained after 2.5‐60 min are the same, which indicate short chain lifetime. The values of