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Metallocene complexes as catalysts for olefin polymerization

✍ Scribed by Helmut G. Alt

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
48 KB
Volume
250
Category
Article
ISSN
0010-8545

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πŸ“œ SIMILAR VOLUMES

Metallacyclic metallocene complexes as c
Metallacyclic metallocene complexes as catalysts for olefin polymerization
✍ Helmut G. Alt; Erik H. Licht; Andrea I. Licht; Katharina J. Schneider πŸ“‚ Article πŸ“… 2006 πŸ› Elsevier Science 🌐 English βš– 553 KB

Metallacyclic metallocene complexes of titanium, zirconium and hafnium can be prepared by hydrogen elimination processes of suitable substituents such as -phenylalkyl or -alkenyl at the aromatic ligands. In some cases, the intermediates containing agostic hydride ligands can be isolated and characte

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Pentalene substituted metallocene comple
Pentalene substituted metallocene complexes for olefin polymerization
✍ Walter Kaminsky; Oliver Sperber; Ralf Werner πŸ“‚ Article πŸ“… 2006 πŸ› Elsevier Science 🌐 English βš– 265 KB

Pentalene bridged zirconocene/methylaluminoxane catalysts are described as useful for the polymerization of ethene, propene, and copolymerizations with norbornene. They show a high thermostability up to polymerization temperatures of 105 β€’ C. Polyethylenes with molecular masses of 4 million g/mol ar