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Metalation reactions : V. Product distribution in the metalation of alkoxy(alkylthio)benzenes

✍ Scribed by S. Cabiddu; S. Melis; P.P. Piras; F. Sotgiu

Book ID: 108354441
Publisher: Elsevier Science
Year: 1979
Tongue: English
Weight: 551 KB
Volume: 182
Category: Article
ISSN: 0022-328X
DOI: 10.1016/s0022-328x(00)94378-x

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## Abstract In the reactions of Grignard reagents and __n__‐butyllithium the presence of transition metals and complexing solvents facilitates the formation of anion radicals. High radical concentrations, observable for some days at laboratory temperature, and very well resolved e.s.r. spectra of t