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Metalation of Biginelli Compounds. A General Unprecedented Route to C-6 Functionalized 4-Aryl-3,4-dihydropyrimidinones.

✍ Scribed by Kamaljit Singh; Sukhdeep Singh; Aman Mahajan


Publisher
John Wiley and Sons
Year
2005
Weight
35 KB
Volume
36
Category
Article
ISSN
0931-7597

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Homoleptic trimethylphosphane complexes of transition metals, such as [Mo(PMe 3 ) 6 ] (2-Mo) [1] and [W(PMe 3 ) 6 ] (2-W), [2] form a class of rare and very reactive compounds. [3][4][5] The high reactivity of these complexes originates from the combination of strong s-donor and weak p-acceptor prop