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Metalation of 9-Oxabicyclo[3.3.1]nonadiene – the Deprotonation Path to Bridgehead Olefins

✍ Scribed by Ghada Bassioni; Frank H. Köhler

Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
172 KB
Volume
2006
Category
Article
ISSN
1434-193X

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## Abstract In view of the significance of steric compression in the base‐catalyzed intramolecular cyclization of polycyclic olefinic alcohols, the standard enthalpies of formation of __anti__^9,10^‐10 __endo__‐hydroxytricyclo [4.2.1.1^2,5^]deca‐3,7‐dien‐9‐one **(1)** and 9‐oxatetracyclo [5.4.0.0^3