Metalated Epoxides as Carbenoids. Competing C—H and C=C Insertion in α-Alkoxy Epoxide Systems.
✍ Scribed by Luc Dechoux; Claude Agami; Eric Doris; Charles Mioskowski
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 132 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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📜 SIMILAR VOLUMES
Metalated Epoxides as Carbenoids. Solvent Effect on the Alkyl 1,2-Shift in α-Hydroxy Epoxide Systems. -The BuLi-mediated carbenoid alkyl 1,2-rearrangement of the deuterated α-hydroxy epoxide (I) is investigated in detail. The process is strongly affected by solvation of the lithium atoms, which is
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