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ChemInform Abstract: Metalated Epoxides as Carbenoids. Solvent Effect on Competing Intramolecular C—H and Intermolecular C—Li Insertions in α-Alkoxy Epoxide Systems.

✍ Scribed by Luc Dechoux; Claude Agami; Eric Doris; Charles Mioskowski


Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Metalated Epoxides
✍ E. DORIS; C. MIOSKOWSKI; L. DECHOUX; C. AGAMI 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB

Metalated Epoxides as Carbenoids. Solvent Effect on the Alkyl 1,2-Shift in α-Hydroxy Epoxide Systems. -The BuLi-mediated carbenoid alkyl 1,2-rearrangement of the deuterated α-hydroxy epoxide (I) is investigated in detail. The process is strongly affected by solvation of the lithium atoms, which is