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Metal substituted diazo esters as substrates for cross coupling reactions

✍ Scribed by Albert Padwa; Marcus M. Sá; M. David Weingarten

Book ID
108374568
Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
924 KB
Volume
53
Category
Article
ISSN
0040-4020

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ChemInform Abstract: Metal-Substituted D
ChemInform Abstract: Metal-Substituted Diazo Esters as Substrates for Cross Coupling Reactions.
✍ A. PADWA; M. M. SA; M. D. WEINGARTEN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

Metal-Substituted Diazo Esters as Substrates for Cross Coupling Reactions. -The Hg compound (I) reacts with acid halides to yield diazo β-ketoesters, e.g. (III). Substitution reaction of (IIIa) with various nucleophiles affords the corresponding derivatives, such as (IV), (VI), (VIII), and (X). Base