Metal ions and hydrogen peroxide. XX. On the kinetics and mechanism of the decomposition of hydrogen peroxide, catalyzed by the Cu2+-2,2'-bipyridyl complex
β Scribed by Sigel, Helmut; Flierl, Claus; Griesser, Rolf
- Book ID
- 120321801
- Publisher
- American Chemical Society
- Year
- 1969
- Tongue
- English
- Weight
- 444 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The rate of reaction of (Fe(DTPA)) with Hz02 was investigated at various temperatures. The observed rate law is given by the expression. The rate constants and the related thermodynamic parameters are calculated. Substitution controlled mechanisms are suggested to account for the formation of the v
Oscillatory change of pH occurs during the chromate-catalyzed decomposition of hydrogen peroxide in a weakly acidic medium at elevated temperature and at high initial concentration of hydrogen peroxide. In a closed system, there are only two or three periods, but sustained oscillation occurs in a CS