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Metal-ion interaction with penicillins: Kinetics of complexation of nickel(II)

✍ Scribed by G. V. Fazakerley; G. E. Jackson

Publisher
John Wiley and Sons
Year
1977
Tongue
English
Weight
352 KB
Volume
66
Category
Article
ISSN
0022-3549

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✦ Synopsis

The kinetics of complexation of nickel(II) with some penicillins and related compounds show that the zwitterionic form of the ligand has very low reactivity compared to the anionic form. The resolved rate constants are interpreted in terms of binding to the ring nitrogen and carboxyl group and not to the side chain.

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