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Metal ion catalysed acid hydrolysis of acidopentaammine cobalt(III) complexes: Kinetics and mechanism of Al(III), Ga(III) and In(III) catalysed hydrolysis of malonatopentaamminecobalt(III) complex

✍ Scribed by A.C. Dash; R.K. Nanda


Book ID
115973855
Publisher
Elsevier Science
Year
1975
Weight
362 KB
Volume
37
Category
Article
ISSN
0022-1902

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The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-