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Kinetics and mechanism of acid catalysed dissociation of some octahedral complexes of cobalt(III) and chromium(III)

✍ Scribed by Anuradha Dhur; Sarmistha Das; R. N. Banerjee; D. Banerjea


Publisher
Springer
Year
1982
Tongue
English
Weight
418 KB
Volume
7
Category
Article
ISSN
0340-4285

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Kinetics and mechanism of the acid-catal
✍ Eleonora Danilczuk; Janusz ChatΕ‚as πŸ“‚ Article πŸ“… 1996 πŸ› Springer 🌐 English βš– 431 KB

The kinetics of the acid-catalysed hydrolysis of the [(imidazole)4Co(CO3) ] + ion was found to follow the rate law -dln[complex]/dt = k~K[H+]/(1 + K[H+]) in the 25-45 ~ range, [H +] 0.05-1.0 M range and I = 1.0 M. The reaction sequence consists of a rapid protonation equilibrium followed by the one-