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Metal complexes with macrocyclic ligands. Part XXV. One-step synthesis of mono-N-substituted azamacrocycles with a carboxylic group in the side-chain and their complexes with Cu2+ and Ni2+

✍ Scribed by Martin Studer; Thomas A. Kaden


Publisher
John Wiley and Sons
Year
1986
Tongue
German
Weight
357 KB
Volume
69
Category
Article
ISSN
0018-019X

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Metal Complexes with Macrocyclic Ligands
✍ Daniel Tschudin; Andreas Riesen; Thomas A. Kaden πŸ“‚ Article πŸ“… 1989 πŸ› John Wiley and Sons 🌐 German βš– 433 KB πŸ‘ 1 views

The X-ray structures of the Cuz+ complexes of 1,4,8,11 -tetraazacyclotetradecane derivatives with an ethylpropionate and diethylphosphonate group, 5 and 6, respectively, indicate that the metal ion is pentacoordinated by the four N-atoms of the macrocycle and one 0-atom. In the case of 5, it is the