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Metal complexes with macrocyclic ligands. Part XXII. Synthesis two of bis-tetraaza-macrocycles and study of the structures, electrochemistry, VIS and EPR spectra of their binuclear Cu2+ and Ni2+ complexes

✍ Scribed by Renè Schneider; Andreas Riesen; Thomas A. Kaden

Publisher: John Wiley and Sons
Year: 1986
Tongue: German
Weight: 498 KB
Volume: 69
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19860690108

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## Abstract The interaction of solvents and of unidentate ligands such as N, SCN^−^, OCN^−^ and OH^−^ with the Co^2+^‐, Ni^2+^ and Cu^2+^‐complexes of 1,4,8,11‐tetramethyl‐1,4,8,11‐tetraazacyclotetradecane (TMC) have been studied by Spectrophotometric and calorimetric techniques. The spectra in dif