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Metal-Cation-Mediated Hydrolysis of Phosphonoformate Diesters: Chemoselectivity and Catalysis 1

✍ Scribed by Moss, Robert A.; Morales-Rojas, Hugo; Vijayaraghavan, Saketh; Tian, Jingzhi

Book ID: 120008950
Publisher: American Chemical Society
Year: 2004
Tongue: English
Weight: 275 KB
Volume: 126
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja030437h

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## Abstract Monocationic bis‐allyl complexes [Ln(η^3^‐C~3~H~5~)~2~(thf)~3~]^+^[B(C~6~X~5~)~4~]^−^ (Ln=Y, La, Nd; X=H, F) and dicationic mono‐allyl complexes of yttrium and the early lanthanides [Ln(η^3^‐C~3~H~5~)(thf)~6~]^2+^[BPh~4~]~2~^−^ (Ln=La, Nd) were prepared by protonolysis of the tris‐allyl