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Metal-Catalyzed Synthesis of Alternating Copolymers

✍ Scribed by Emilie Brulé; Jia Guo; Geoffrey W. Coates; Christophe M. Thomas

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
460 KB
Volume
32
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

The creation of polymers with a high degree of sequence and/or stereocontrol represents an exciting frontier in materials science. In order to obtain alternating polymers, coordination polymerization using well‐defined metal complexes has played a leading role in the last two decades. In the following paper, we will describe selected published efforts to achieve these research goals using discrete, structurally well‐characterized metal complexes.
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Synthesis of phosphorus-containing alter
Synthesis of phosphorus-containing alternating copolymers
✍ A. Mahammad Ibrahim; V. Mahadevan; M. Srinivasan 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 202 KB

Phosphorus-containing alternating copolymers were synthesized by the reaction of nucleophilic monomers M N with electrophilic monomers M E. Methyl acrylate and v-butyrolactone were used as M E monomers, with 2-(4-methylphenyl)-l,3,2-dioxaphospholane and 2-(4-methylphenyl)-4-methyl-l,3,2dioxaphosphol