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Metal-catalysed organic photoreactions. Photoreaction of ??-unsaturated ketones in alcohols in the presence of titanium(IV) chloride

✍ Scribed by Sato, Tadashi; Izumi, Giichi; Imamura, Takashi


Book ID
121503643
Publisher
Royal Society of Chemistry
Year
1976
Weight
514 KB
Volume
7
Category
Article
ISSN
1472-7781

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## Abstract Photochemical reactions of theophylline with dialkyl and cyclic ethers in the presence of aliphatic ketones result in substitution of the hydrogen atom at C‐8 position. The results indicate that both the α‐alkoxyalkyl radicals derived by H‐abstraction from ether and the ketyl radicals g