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Metal catalysed alkylation of alkenes

✍ Scribed by R.H. Cunningham; A.V.G. Mangnus; J. van Grondelle; R.A. van Santen


Book ID
108023519
Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
701 KB
Volume
21
Category
Article
ISSN
0920-5861

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πŸ“œ SIMILAR VOLUMES


Transition metal catalysed alkylation of
✍ Ronald Grigg; Vladimir Savic πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 149 KB

Healing 3-or 4-acetyl pyridine with alkenes in toluene in the presence of 5-10mo1% of RulI2CO(PPh3) 3 ",fffixdcd the mono-or a mixture of mono-and di-alkylaw.d products in good yield. Alkylation of acctylindole derivatives was also achieved with similar efficiency.

The stereochemistry of metal catalysed h
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Reactions of both terminal and cyclic alkenes have been shown to occur in a stereospecifically cis -manner with deuterium cyanide when a catalyst system based on -Pd(DIOP), was used. Reactions of cyclohexene give only the products of equatorial cyanide incorporation.