Metal catalysed alkylation of alkenes
β Scribed by R.H. Cunningham; A.V.G. Mangnus; J. van Grondelle; R.A. van Santen
- Book ID
- 108023519
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 701 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0920-5861
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π SIMILAR VOLUMES
Healing 3-or 4-acetyl pyridine with alkenes in toluene in the presence of 5-10mo1% of RulI2CO(PPh3) 3 ",fffixdcd the mono-or a mixture of mono-and di-alkylaw.d products in good yield. Alkylation of acctylindole derivatives was also achieved with similar efficiency.
Reactions of both terminal and cyclic alkenes have been shown to occur in a stereospecifically cis -manner with deuterium cyanide when a catalyst system based on -Pd(DIOP), was used. Reactions of cyclohexene give only the products of equatorial cyanide incorporation.