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Metal carbonyl-promoted rearrangement of cyclopropenes to naphthols

โœ Scribed by Semmelhack, M. F.; Ho, Suzzy; Steigerwald, Michael; Lee, M. C.


Book ID
126120341
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
387 KB
Volume
109
Category
Article
ISSN
0002-7863

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Transition metal promoted rearrangement
โœ Michael A. McKinney; S.K. Chou ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 165 KB

We wish to report the first example of a zinc-catalyzed rearrangement of the bicycle [P.l.O]pentane ring system. Namely, the rearrangement of I-Phenylbicyclo[2.1.O]pentane(b) with a catalytic amount of zinc iodide in benzene (2 hr, 60') to give as the sole product 3-phenylcyclopentene(2a).