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Mechanism of photochemical rearrangements of 3-substituted cyclopropenes to cyclopentadienes

โœ Scribed by Ming-Der Su

Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
528 KB
Volume
51
Category
Article
ISSN
0040-4020

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โœ Albert Padwa; Roman Loza; Daniel Getman ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 201 KB

During the course of our studies dealing with the photochemical transformations of small ring compounds, we uncovered an unusual substituent effect on the mode of ring opening of an unsymmetrically substituted cyclopropene. 192 Thus, the major product obtained from the irradiation of 1 was derived f