Metal Carbene Reactions from Dirhodium(II) Catalysts
β Scribed by Michael P. Doyle
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
The synthesis and X-ray structure of the binucledr complex tetrakis[(4S)-4-phenyloxazolidin-2-one]dirhodium(I1) ([Rh2{(4S)-phox},]) are reported. Structure-selectivity comparisons are made for typical metal carbcne transformations, such as inter-and intramolecular cyclopropane formation, intermolecu
Novel Unsymmetrical ortho-Metalated Dirhodium(II) Catalysts: trans Influence of the Axial Ligand. -The Rh-catalyzed decomposition of the diazoketone (I) resulting in formation of the bicyclic ketone (II) is investigated in detail. The inductive effect of X axial groups which are transmitted through