Metal-bridging benzene in a binuclear hydridovanadium complex
β Scribed by Jonas, Klaus; Wiskamp, Volker; Tsay, Yi Hung; Krueger, Carl
- Book ID
- 126035460
- Publisher
- American Chemical Society
- Year
- 1983
- Tongue
- English
- Weight
- 265 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
The structural features of the novel dinuclear complexes (Scheme 1) have been established by IR-, 'H-NMR, 13C-NMR and mass spectroscopy. Aside from spectroscopic characterization, the structure of 3a has been examined by single-crystal X-ray diffraction techniques (Fig. 1). The P" w Fig. I . Crystal
Based on a symmetry argument, we study ground states of what we call MMX-chain compounds, which are the new class of halogen-bridged metal complexes. Commensurate density-wave solutions of a relevant multi-band Peierls-Hubbard model are systematically revealed within the Hartree-Fock approximation.