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A Binuclear Complex with a Thioformaldehyde Bridge

✍ Scribed by Prof. Dr. Max Herberhold; Wolfgang Ehrenreich; Wolfgang Bühlmeyer

Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
240 KB
Volume
22
Category
Article
ISSN
0044-8249

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✦ Synopsis

The structural features of the novel dinuclear complexes (Scheme 1) have been established by IR-, 'H-NMR, 13C-NMR and mass spectroscopy. Aside from spectroscopic characterization, the structure of 3a has been examined by single-crystal X-ray diffraction techniques (Fig. 1). The P" w Fig. I . Crystal structure of the novel p2,q2-selenoformaldehyde complex 3a.

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The acetoxymethyl rhodium compounds [(η 5 -the formaldehyde compounds [(η 5 -C 5 R 5 )Rh(η 2 -CH 2 O)(L)] (24-27). The related thioformaldehyde complexes [(η 5 -C 5 R 5 )Rh(CH 2 OAc)(L)I] (4, 13-16) which were prepared from the chloromethyl derivatives [(η 5 -C 5 R 5 )Rh(CH 2 Cl)(L)I] and C 5 Me 5 )