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Metal bis(perfluorooctanesulfonyl)amides as highly efficient Lewis acid catalysts for fluorous biphase organic reactions

✍ Scribed by Xiuhua Hao; Akihiro Yoshida; Joji Nishikido


Book ID
108170408
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
207 KB
Volume
127
Category
Article
ISSN
0022-1139

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Sn[N(SO 2 C 8 F 17 ) 2 ] 4 catalyst was shown to give an excellent yield and selectivity in a fluorous biphasic catalytic system for Baeyer-Villiger oxidation of cyclic ketones by 35% aqueous hydrogen peroxide, a green, safe and cheap oxidant. Furthermore, the catalyst was completely recovered and r