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Metal atom clusters III. The acceptor properties and bonding of (Mo6Cl8)4+ and (Nb6Cl12)2+ clusters

✍ Scribed by R.A. Field; D.L. Kepert; D. Taylor


Book ID
114041385
Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
563 KB
Volume
4
Category
Article
ISSN
0020-1693

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Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] Β΄n EtOH Β΄m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 Β΄6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The