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Metal-ammonia reduction and reductive alkylation of 2-furoic acid
β Scribed by Arthur J. Birch; Jacob Slobbe
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- French
- Weight
- 100 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0040-4039
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Stereoselectivity in the Birch Reduction of 2-Furoic Acid Derivatives. -Birch reduction of the chiral amide (I) of 2-furoic acid and following electrophilic quench gives the dihydrofuroic amides (III) with high diastereoselectivity. Acidic cleavage of the chiral auxiliary liberates the carboxylic a
The products of reduction and reductive alkylation of five demineralized coals run in a system of potassium/ liquid ammonia were subject to extraction by methylene chloride and n-pentane. The paper reports infrared and nuclear magnetic resonance (n.m.r.) characteristics of the extracts and the resul