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Metabolism in porifera IV. Biosynthesis of the 3β-Hydroxymethyl-A-nor-5α-Steranes from cholesterol byAxinella verrucosa

✍ Scribed by M. De Rosa; L. Minale; G. Sodano


Book ID
112670620
Publisher
Springer
Year
1975
Tongue
English
Weight
284 KB
Volume
31
Category
Article
ISSN
1420-682X

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Through appropriate labeling experiments, it was shown that the unusual sterol 3B-(hydroxymethyl)-A-nor-Sa-cholest-15-ene ( 1) is generated by ring contraction of dietary cholesterol followed by the introduction of the 15-16 double bond, rather than by ring contraction of 15-dehydrocholesterol (4).