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Mesomorphic Cyclometalated (Cyclopentadienyl)palladium and -platinum Complexes

✍ Scribed by Mauro Ghedini; Francesco Neve; Daniela Pucci

Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
355 KB
Volume
1998
Category
Article
ISSN
1434-1948

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✦ Synopsis

The mesogenic 4, 4Ј-bis[4-(n-octyloxy)benzoyloxy]azobenzene (HL) ligand reacts with [(PhCN) 2 PdCl 2 ] to give the dinuclear cyclometalated complex [(¡-Cl)(L)Pd] 2 (1), from which the mononuclear half-sandwich [(η 5 -C 5 H 5 )(L)Pd] (2) species has been obtained by reaction with Tl(C 5 H 5 ). The Pt II analogue of 2, [(η 5 -C 5 H 5 )(L)Pt] (4), has been prepared in a

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