Mesoionic compounds. XXXVI. Reaction of mesoionic systems with diphenylcyclopropene derivatives
β Scribed by Potts, K. T.; Baum, J.; Houghton, E.
- Book ID
- 121860795
- Publisher
- American Chemical Society
- Year
- 1976
- Tongue
- English
- Weight
- 967 KB
- Volume
- 41
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
We studied the behaviour of bicyclic mesoionic compounds derived from the cyclodehydration of cyclic N-acyl-~-aminoacids 1-4 with N-(phenylmethylene)benzenesulfonamide 5. The reaction affords spirocyΒ’lic [5-1actams and/or imidazo-condensed products (the 1,3-dipolar cycloaddition adducts) depending o
of either N-benzoylalanine or N-acetylphenylgllcine. The preparative application of this new pyrrole synthesis is simplified by the fact that alkyloxazolones, which are unstable and difficult lo purify [I], can be used in sifu. Thus, (5) is obtained by the reaction of phenylglycine or N-acetylphenyl