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Merocyanine ↔ spiropyran transformation in a polymer matrix: An example of a dispersive chemical reaction

✍ Scribed by R. Richert; H. Bässler

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
503 KB
Volume
116
Category
Article
ISSN
0009-2614

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✦ Synopsis

The non-exponential time dependence of spiropyran e merocyanine transformation in a co-polymer has been reinvestigated experimentally and analysed in terms of a disp_ersive first-order chemical feacrion. Non-exponential dependence can be accounted for by a Gaussian distribution of activation energies whose width decreases with increasing temperature.

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