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Mercury in organic chemistry VIII. A convenient synthesis of ∝,β-unsaturated ketones

✍ Scribed by Richard C. Larock; John C. Bernhardt

Publisher
Elsevier Science
Year
1976
Tongue
French
Weight
216 KB
Volume
17
Category
Article
ISSN
0040-4039

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✦ Synopsis

Recently, vinylmercurials have become available by a variety of acetylene addition reactions.3-6

These reactions appear to accommodate con-

'HgCl siderable organic functionality.

The vinylmercurials themselves possess a number of characteristics making them attractive as synthetic intermediates.

Recently we reported that they can be readily converted into a,,B-unsaturated carboxylic acids and esters in excellent yield.7 We now wish -Lo report

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