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Mercuric acetate cleavage of sulfur-donor ligand ortho-metalated complexes

✍ Scribed by Howard Alper; William G. Root

Book ID
104234863
Publisher
Elsevier Science
Year
1974
Tongue
French
Weight
143 KB
Volume
15
Category
Article
ISSN
0040-4039

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✦ Synopsis

Treatment of thiobenzophenones [I -Scheme l] with diiron enneacarbonyl at room temperature gives sulfur-donor ligand ortho+netalated complexes [II] in very good yie1ds.l Isobenzothiophene derivatives were obtained by oxidative or photolytic cleavage of II. We now wish

πŸ“œ SIMILAR VOLUMES

A carbon-13 n.m.r. study of sulfur-donor
A carbon-13 n.m.r. study of sulfur-donor ligand ortho-metalated iron carbonyl complexes
✍ Howard Alper πŸ“‚ Article πŸ“… 1976 πŸ› John Wiley and Sons 🌐 English βš– 137 KB

## Abstract Carbon‐13 n.m.r. data are reported for a series of sulfur‐donor ligand __ortho__‐metalated iron carbonyl complexes derived from thiobenzophenones. The chemical shift Ξ΄153Β·5–161Β·4 for the aromatic carbon σ‐bonded to iron is readily identified, and occurs in the same region as the signal