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A carbon-13 n.m.r. study of sulfur-donor ligand ortho-metalated iron carbonyl complexes

✍ Scribed by Howard Alper

Book ID
102524476
Publisher
John Wiley and Sons
Year
1976
Tongue
English
Weight
137 KB
Volume
8
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

Carbon‐13 n.m.r. data are reported for a series of sulfur‐donor ligand ortho‐metalated iron carbonyl complexes derived from thiobenzophenones. The chemical shift δ153·5–161·4 for the aromatic carbon σ‐bonded to iron is readily identified, and occurs in the same region as the signal for the corresponding carbon in a related nitrogen‐donor ligand complex. The benzylic carbon gives a signal at δ62·8–63·3, subject to the nature of the complex.

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