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Mercuri-desilylation of chiral cyclopropylmethylsilanes

โœ Scribed by Yannick Landais; Liliana Parra-Rapado

Publisher
Elsevier Science
Year
1996
Tongue
French
Weight
247 KB
Volume
37
Category
Article
ISSN
0040-4039

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๐Ÿ“œ SIMILAR VOLUMES

Studies on the Mercury-Desilylation of C
Studies on the Mercury-Desilylation of Chiral Cyclopropylmethylsilanes - A Stereocontrolled Access to Carba-Sugars
โœ Yannick Landais; Liliana Parra-Rapado ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 575 KB

Scheme 16 stereospecific mercury-desilylation of the cyclopropylmethylsilanes offers an entry to homoallylic derivatives which can be versatile synthons for organic synthesis. This was demonstrated through a short and stereoselective access to carba-sugars, to precursors of carba-nucleosides and to