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ChemInform Abstract: Studies on the Mercury-Desilylation of Chiral Cyclopropylmethylsilanes — A Stereocontrolled Access to Carba-Sugars.

✍ Scribed by Yannick Landais; L. Parra-Rapado


Publisher
John Wiley and Sons
Year
2010
Weight
41 KB
Volume
31
Category
Article
ISSN
0931-7597

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Studies on the Mercury-Desilylation of C
✍ Yannick Landais; Liliana Parra-Rapado 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 English ⚖ 575 KB

Scheme 16 stereospecific mercury-desilylation of the cyclopropylmethylsilanes offers an entry to homoallylic derivatives which can be versatile synthons for organic synthesis. This was demonstrated through a short and stereoselective access to carba-sugars, to precursors of carba-nucleosides and to