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Medium Effects on the Electron-Transfer Reactions between cis-Co(NH3)4(H2O)32+ and the Donors Fe(CN)4-6 and Mo(CN)4-8

✍ Scribed by Manuel Galan; Maria Del Mar Graciani; Rafael Jiménez; M. Luisa Moyá; Ernestina Muñoz; Amalia Rodriguez; Francisco Sánchez

Book ID: 112008273
Publisher: Wiley (John Wiley & Sons)
Year: 1996
Tongue: English
Weight: 582 KB
Volume: 100
Category: Article
ISSN: 0372-8323
DOI: 10.1002/bbpc.19961000411

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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4−^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3−^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__