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Thermal reactions of metal complexes under quasi-isothermal and -isobaric conditions. 3. Solid-phase thermal reactions of the doubly complexed salts of the forms [(Cr or Co)(NH3)6][(Cr or Co)(CN)6], [(Cr or Co)(H2O)(NH3)5][(Cr or Co)(CN)6], and cis-[(Co(H2O)2(NH3)4][Co(CN)6]

✍ Scribed by Uehara, Akira; Terabe, Seiji; Tsuchiya, Ryokichi


Book ID
126071895
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
727 KB
Volume
22
Category
Article
ISSN
0020-1669

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## Abstract The kinetics of electron transfer reactions between [Fe(CN)~6~]^4βˆ’^ and [Co(NH~3~)~5~pz]^3+^ and between [Ru(NH~3~)~5~pz]^2+^ and [Co(C~2~O~4~)~3~]^3βˆ’^ was studied in concentrated salt solutions (Na~2~SO~4~, LiNO~3~, and Ca(NO~3~)~2~). An analysis of the experimental kinetic data, __k__