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Medium effects in the acid-catalyzed hydrolysis of phenylacetohydroxamic acid in aqueous sulfolane

✍ Scribed by Berndt, D. C.


Book ID
126406277
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
289 KB
Volume
39
Category
Article
ISSN
0022-3263

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Rate constants and activation parameters for the acid-catalyzed hydrolysis of eight ringsubstituted diazoacetophenones have been measured in three dioxan-water mixtures. An isokinetic relationship applies to the results obtained using a 50% dioxan-water mixture as solvent. Solvent and substituent ef